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LBO Crystal

Short Description:

LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.


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LBO (LiB3O5) is a kind of non-linear optical crystal with good ultraviolet transmittance (210-2300 nm), high laser damage threshold and large effective frequency doubling coefficient (about 3 times of KDP crystal). So LBO is commonly used to produce high power second and third harmonic laser light, especially for ultraviolet lasers.

LBO has large band gap and transparency region, high non-linear coupling, good chemical and mechanical properties. These features make this crystal capable of optical parametric processes (OPO/OPA) and noncritical phase matching (NCPM), too.

Contact us for the best solution for your application of LBO crystals.

WISOPTIC Capabilities -LBO

• Large aperture: max 20x20 mm

• Various size: max length 60 mm

• End configuration: flat, or Brewster, or specified

• High transmittance: AR coating with R<0.1% (at 1064/532nm)

• Mounting: upon request

• Very competitive price

WISOPTIC Standard Specifications* - LBO 

Dimension Tolerance ± 0.1 mm
Angle Tolerance < ± 0.25°
Flatness < λ/8 @ 632.8 nm
Surface Quality < 10/5 [S/D]
Parallelism < 20”
Perpendicularity ≤ 5'
Chamfer ≤ 0.2mm @ 45°
Transmitted Wavefront Distortion < λ/8 @ 632.8 nm
Clear Aperture > 90% central area
Coating AR coating or Broad Band AR-coating

R<0.1% @ 1064 nm, R<0.1% @ 532 nm, R<0.5% @ 355 nm

Laser Damage Threshold > 10 GW/cm2 for 1064nm, 10ns, 10Hz (polished only)
> 1.0 GW/cm2 for 1064nm, 10ns, 10Hz (AR-coated)
> 0.5 GW/cm2 for 532nm, 10ns, 10Hz (AR-coated)
* Products with special requirement upon request.
LBO_4297
LBO-1
LBO-2

Main Features - LBO

• Broad transparency range from 160 nm to 2.6 µm

• High optical homogeneity, free of inclusion

• Relatively large effective SHG coefficient (about three times that of KDP)

• Broad wavelength range of Type I and Type II non-critical phase matching (NCPM)

• Wide acceptance angle, small walk-off

• High laser damage threshold

Comparison of bulk damage threshold [1064nm, 1.3ns]

Crystals

Energy fluence (J/cm²)

Power density (GW/cm²)

KTP

6.0

4.6

KDP

10.9

8.4

BBO

12.9

9.9

LBO

24.6

18.9

Primary Applications - LBO

• Either Type I or Type II frequency doubling (SHG) and sum frequency generation (SFG) of high peak power Nd-doped (Nd:YVO4, Nd:YAG, Nd:YLF), Ti:Sapphire, Alexandrite and Cr:LiSAF lasers

• Third harmonic generation (THG) of Nd-doped lasers

• Temperature-controllable non-critical phase matching (NCPM) for 1.0–1.3 µm

• Room temperature NCPM for Type II SHG at 0.8–1.1 µm

• Widely tunable OPO/OPA for both Type I and Type II phase matching

Physical Properties - LBO

Chemical formula LiB3O5
Crystal structure Orthorhombic
Point group mm2
Space group Pna21
Lattice constants a=8.46 Å, b=7.38 Å, c=5.13 Å, Z=2
Density 2.474 g/cm3
Melting point 835 °C
Mohs hardness 6
Thermal conductivity 3.5 W/(m·K)
Thermal expansion coefficients αx=10.8x10-5/K, αy=-8.8x10-5/K, αz=3.4x10-5/K
Hygroscopicity Slightly hygroscopic

Optical Properties - LBO

Transparency region
  (at “0” transmittance level)
155-3200 nm
Refractive indices 1064 nm  532 nm  355 nm

nx=1.5656

ny=1.5905
nz=1.6055

nx=1.5785

ny=1.6065
nz=1.6212

nx=1.5973

ny=1.6286
nz=1.6444

Linear absorption coefficients

350~360 nm 

1064 nm 

α = 0.0031 /cm α < 0.00035 /cm

NLO coefficients (@ 1064 nm)

d31 = 1.05±0.09 pm/V, d32 = -0.98±0.09 pm/V,
d33 = 0.05±0.006 pm/V

 


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